Copper(<scp>ii</scp>) tetrakis(pentafluorophenyl)porphyrin: highly active copper-based molecular catalysts for electrochemical CO<sub>2</sub> reduction
Kento Kosugi, Hina Kashima, Mio Kondo, Shigeyuki Masaoka
Abstract
) of 0.85 V. Surprisingly, this value is more than 1 000 000 times higher than those of other reported copper-based molecular catalysts.
Topics & Concepts
OverpotentialCatalysisElectrochemistryReduction (mathematics)ChemistryInorganic chemistryElectrodeChemical engineeringMaterials scienceOxygen reduction reactionElectrocatalystActive siteValue (mathematics)Peak currentChemical reductionReaction conditionsCombinatorial chemistryFuel cellsCO2 Reduction Techniques and CatalystsCarbon dioxide utilization in catalysisMetalloenzymes and iron-sulfur proteins