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A triphenylamine-based Pt(<scp>ii</scp>) metallacage <i>via</i> coordination-driven self-assembly for nonlinear optical power limiting

Zihao Yin, Xingmao Chang, Jianyang Zang, Simin Lin, Zhijie Zhou, Taihong Liu, Liping Ding, Haonan Peng, Yu Fang

2022Journal of Materials Chemistry C16 citationsDOI

Abstract

A beautiful 3D metallacage was designed and synthesized via coordination-driven assembly. The metallacage showed a larger 2PA cross-section that was about 2.4-fold that of the ligand, and better optical limiting performance and photo-stability.

Topics & Concepts

TriphenylamineLimitingMaterials scienceLigand (biochemistry)Nonlinear systemNonlinear opticalOptical powerPower (physics)OptoelectronicsOpticsPhysicsChemistryReceptorEngineeringLaserThermodynamicsQuantum mechanicsMechanical engineeringBiochemistryNonlinear Optical Materials StudiesPorphyrin and Phthalocyanine ChemistryGold and Silver Nanoparticles Synthesis and Applications
A triphenylamine-based Pt(<scp>ii</scp>) metallacage <i>via</i> coordination-driven self-assembly for nonlinear optical power limiting | Litcius