Sulfur-bridge ligands altering the microenvironment of single-atom CoN<sub>3</sub>S sites to boost the oxygen reduction reaction
Feng Liu, Yingchun Guo, Yan Zhong, Jingsha Li, Heng Zhang, Lei Shi, Xuanni Lin, Fenghui Ye, Kai Ge, Shuai Yuan, Chuangang Hu, Chunxian Guo
Abstract
-S moiety facilitates the ORR kinetics by optimizing the adsorption of intermediates. This work provides new insights into the design of single-atom catalysts for electrocatalysis through heteroatom-bridge ligand engineering.
Topics & Concepts
ChemistrySulfurDesorptionAdsorptionOxygenBoosting (machine learning)Combinatorial chemistryOxygen atomBridge (graph theory)PhotochemistryPhysical chemistryMoleculeOrganic chemistryComputer scienceMedicineMachine learningInternal medicineElectrocatalysts for Energy ConversionFuel Cells and Related MaterialsAdvanced Photocatalysis Techniques