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Forecast of Phase Diagram for the Synthesis of a Complex for the Detection of Cr<sup>6+</sup> Ions

Sumit Kumar Chaudhary, R.N. Rai, Kedar Sahoo, Manoj Kumar

2022ACS Omega10 citationsDOIOpen Access PDF

Abstract

C NMR studies. The significant thermodynamic parameters such as the heat of mixing, the entropy of fusion, the roughness parameter, the interfacial energy, and excess thermodynamic functions have been studied. The novel complex (ANNBA) material displayed intense fluorescent emission as compared to the parent and the other well-known fluorescent organic material "pyrene." The influence of solvent's polarity on the absorption and emission of the complex has been studied in different solvents. Herein, we have displayed remarkable affinity of the complex toward hexavalent chromium ions in water, affecting its fluorescent property. We have deployed the synthesized complex as a turn-off fluorescent sensor to detect the most hazardous hexavalent chromium ions in water for the first time.

Topics & Concepts

Phase diagramIonPhase (matter)SolventChemistrySolid-statePhysical chemistryInorganic chemistryMaterials scienceOrganic chemistryMolecular Sensors and Ion DetectionPhotochromic and Fluorescence ChemistryPolyoxometalates: Synthesis and Applications
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