Copper-catalyzed,<i>N</i>-auxiliary group-controlled switchable transannulation/nitration initiated by nitro radicals: selective synthesis of pyridoquinazolones and 3-nitroindoles
Adedamola Shoberu, Chengkun Li, Haifeng Qian, Jian‐Ping Zou
Abstract
Within the scope of nitration reactions, the efficiency of sensitive heteroaromatics such as indoles is often eroded by various competitive oxidative decomposition pathways.
Topics & Concepts
NitrationChemistryNitroRadicalCatalysisCopperGroup (periodic table)Medicinal chemistryCombinatorial chemistryOrganic chemistryAlkylCatalytic C–H Functionalization MethodsNanomaterials for catalytic reactionsAsymmetric Hydrogenation and Catalysis