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Probing the Cr3+ luminescence sensitization in β-Ga2O3 with ion-beam-induced luminescence and thermoluminescence

Duarte Magalhães Esteves, Ana Luísa Rodrigues, L.C. Alves, E. Alves, María Isabel Dias, Zhitai Jia, Wenxiang Mu, K. Lorenz, M. Peres

2023Scientific Reports23 citationsDOIOpen Access PDF

Abstract

Abstract Ion-beam-induced luminescence (IBIL) measurements were performed in Cr-doped β -Ga 2 O 3 using both protons and helium ions, showing a strong enhancement of the Cr 3+ luminescence upon ion irradiation. Theoretical modelling of the IBIL intensity curves as a function of the fluence allowed estimating the effective cross-sections associated with the defect-induced IBIL enhancement and quenching processes. The results suggest that sensitizing the Cr 3+ luminescence is more efficient for H + than for He + irradiation. Thermoluminescence (TL) studies were performed in the pristine sample, with no TL signal being observed in the spectral region corresponding to the Cr 3+ emission. In agreement with the IBIL study, upon ion irradiation (with either protons or helium ions), this TL emission is activated. Moreover, it can be quenched by annealing at 923 K for 10 s, thus revealing the role played by the defects induced by the irradiation. These results show that the irradiation-induced defects play a major role in the activation of the Cr 3+ luminescence, a fact that can be exploited for radiation sensing and dosimetry.

Topics & Concepts

LuminescenceThermoluminescenceIrradiationIonMaterials scienceFluenceIon beamOptically stimulated luminescenceAnnealing (glass)Quenching (fluorescence)Analytical Chemistry (journal)RadiochemistryAtomic physicsChemistryOptoelectronicsFluorescenceOpticsPhysicsChromatographyOrganic chemistryComposite materialNuclear physicsGa2O3 and related materialsLuminescence Properties of Advanced MaterialsAdvanced Photocatalysis Techniques
Probing the Cr3+ luminescence sensitization in β-Ga2O3 with ion-beam-induced luminescence and thermoluminescence | Litcius