Evaluating solvothermal and mechanochemical routes towards the metal–organic framework Mg <sub>2</sub> ( <i>m</i> -dobdc)
Elena Chen, Ruth M. Mandel, Phillip J. Milner
Abstract
Mechanochemical and solvothermal routes to the metal–organic framework Mg 2 ( m -dobdc) bearing coordinatively unsaturated Mg( ii ) sites are presented. The mechanochemical synthesis produces porous material exhibiting higher carbon dioxide uptake.
Topics & Concepts
Metal-organic frameworkMetalMaterials scienceChemical engineeringCrystallographyNanotechnologyChemistryMetallurgyOrganic chemistryAdsorptionEngineeringMetal-Organic Frameworks: Synthesis and ApplicationsCovalent Organic Framework ApplicationsMagnetism in coordination complexes