Host–Guest Molecular Recognition at Liquid–Liquid Interfaces
Beibei Wang, Hao Chen, Tan Liu, Shaowei Shi, Thomas P. Russell
Abstract
Host–guest molecular recognition at the liquid–liquid interface endows the interface with unique properties, including stimuli-responsiveness and self-regulation, due to the dynamic and reversible nature of non-covalent interactions. Increasing research efforts have been put into the preparation of supramolecular interfacial systems such as films and microcapsules by integrating functional components (e.g., colloidal particles, polymers) at the interface, providing tremendous opportunities in the areas of encapsulation, delivery vehicles, and biphasic reaction systems. In this review, we summarize recent progress in supramolecular interfacial systems assembled by host–guest chemistry, and provide an overview of the fabrication process, functions, and promising applications of the resultant constructs.