Self-assembly of chiral BINOL cages <i>via</i> imine condensation
E. Ramakrishna, Jiadong Tang, Jia-Ju Tao, Qiang Fang, Zibin Zhang, Jianying Huang, Shijun Li
Abstract
Chiral [2+3] imine cages were constructed via imine condensation from an enantiomeric pair of BINOL-derived dialdehydes and tris(2-aminoethyl)amine and applied in the enantioselective recognition of (1 R ,2 R )- and (1 S ,2 S )-1,2-diaminocyclohexane.
Topics & Concepts
ImineCondensationEnantiomerEnantioselective synthesisAmine gas treatingChemistryTrisStereochemistryMedicinal chemistryCombinatorial chemistryOrganic chemistryCatalysisPhysicsBiochemistryThermodynamicsSupramolecular Chemistry and ComplexesMolecular Sensors and Ion DetectionPorphyrin and Phthalocyanine Chemistry