Molecular engineering of 1D conjugated copper anilate coordination polymers for boosting electrocatalytic nitrate reduction to ammonia
Zhanning Liu, Chengyong Xing, Yufei Shan, Min Ma, Shaowen Wu, Ruixiang Ge, Qingzhong Xue, Jian Tian
Abstract
A series of π–d conjugated copper anilate coordination polymers incorporating different halogen atoms (F, Cl, and Br) were synthesized, with the halogen type significantly affecting the NO 3 RR performance.
Topics & Concepts
Conjugated systemAmmoniaNitrateElectrochemistryChemistryCopperCoordination polymerBoosting (machine learning)Combinatorial chemistryPolymerInorganic chemistryOrganic chemistryElectrodeComputer scienceMachine learningPhysical chemistryAmmonia Synthesis and Nitrogen ReductionAdvanced Photocatalysis TechniquesCovalent Organic Framework Applications