Molecular oxofluorides OMF<sub>n</sub>of nickel, palladium and platinum: oxyl radicals with moderate ligand field inversion
Lin Li, Helmut Beckers, Tony Stüker, Tilen Lindič, Tobias Schlöder, Dirk Andrae, Sebastian Riedel
Abstract
High-valent late transition metal oxo compounds attracted attention because of their peculiar metal–oxygen bond. Their oxo ligands exhibit an electrophilic and distinct radical oxyl (O˙<sup>−</sup>) rather than the more common nucleophilic (O<sup>2−</sup>) character.
Topics & Concepts
PalladiumNickelElectrophileNucleophileRadicalPlatinumTransition metalChemistryLigand (biochemistry)MetalLigand field theoryStereochemistryOrganic chemistryCatalysisReceptorIonBiochemistryMagnetism in coordination complexesPolyoxometalates: Synthesis and ApplicationsMetal-Catalyzed Oxygenation Mechanisms