Investigation of Nd <sup>3+</sup> incorporation in Ce‐rhabdophane: Insight from structural flexibility and occupation mechanism
Hang Liu, Xiaofeng Zhao, Yuancheng Teng, Yuxiang Li, Xiayu Zheng, Shanlin Wang, Lang Wu, Pritam Kumar Panda, Rajeev Ahuja
Abstract
Abstract LnPO 4 · 0.667H 2 O rhabdophane has been considered as a potential material for the precipitation of actinides from radioactive waste liquid, owing to its outstanding characteristics of high actinide bearing and easy synthesis in acid solutions. However, a comprehensive understanding of the actinide occupation and the precipitation response of rhabdophane to remove actinides has yet to be established. In this study, the effect of ions concentration and pH values on the detailed precipitation reaction of Ce x Nd 1‐ x PO 4 · 0.667H 2 O rhabdophane in acid solutions are systematically investigated. Some specific issues such as structural distortion and flexibility, and occupation mechanism are discussed by combining with experiments and density functional theory (DFT) calculation. The results reveal that ions concentration and pH values have a significant impact on the crystallization nucleation step before 12 h. The obtained removal rate of Nd 3+ is more than 99% in pH 1–5 solutions with the ions concentration of 0.05–0.1 mol/L. Moreover, incorporating Nd in CePO 4 · 0.667H 2 O rhabdophane will easily result in the lattice distortion in b ‐axis. DFT calculation and X‐ray photoelectron spectroscopy (XPS) results reveal that Nd is preferentially incorporated in nonhydrated site to form a weaker binding energy of NdO 8 polyhedron.