Modulation of supramolecular chirality by stepwise axial coordination in a nano-size trizinc(<scp>ii</scp>)porphyrin trimer
Avinash Dhamija, Dolly Chandel, Sankar Prasad Rath
Abstract
substrates which suggests that the chirality is dictated solely by the stereographic projection of the chiral center. Interestingly, the long-range electronic communications between the three porphyrin rings generate trisignate CD signals that provide further information about molecular structures.
Topics & Concepts
PorphyrinTrimerSupramolecular chemistryChirality (physics)ChemistryCrystallographySupramolecular chiralityStereochemistryHelicityPhotochemistryCrystal structureDimerPhysicsOrganic chemistryChiral symmetry breakingQuantum mechanicsQuarkNambu–Jona-Lasinio modelParticle physicsPorphyrin and Phthalocyanine ChemistrySynthesis and Properties of Aromatic CompoundsSupramolecular Chemistry and Complexes