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Expansion of Photocatalytic C(sp3)-H Functionalization to Allylation, Alkynylation, and Imination

Yi‐Lun Shih, Sheng-Hao Huang, Yen‐Ku Wu, Ilhyong Ryu

2022Bulletin of the Chemical Society of Japan12 citationsDOI

Abstract

Abstract Photocatalytic C(sp3)-H allylation, alkynylation, and imination using unsaturated benzenesulfonyl compounds were studied using decatungstate anion, W10O324−, as photocatalyst. In all these reactions, site-selective C(sp3)-H bond cleavage was successfully combined with the radical addition/β-scission sequence.

Topics & Concepts

ChemistryAlkynylationBond cleavagePhotocatalysisCleavage (geology)Surface modificationPhotochemistryMedicinal chemistryIonCatalysisOrganic chemistryGeotechnical engineeringPhysical chemistryFracture (geology)EngineeringCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques
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