Metal-free visible-light-induced phosphorylation of unactivated alkyl iodides with white phosphorus as the P-atom source
Fushan Chen, Jialiang Peng, Yue Ying, Yinwei Cao, Pengxiang Xu, Guo Tang, Yufen Zhao
Abstract
This is the first organic-dye-catalyzed alkylation of white phosphorus with unactivated alkyl iodides to afford dialkylphosphines.
Topics & Concepts
White PhosphorusAlkylAlkylationChemistryPhosphorusCatalysisMetalPhotochemistryWhite lightVisible spectrumOrganic chemistryMaterials scienceOptoelectronicsRadical Photochemical ReactionsCatalytic Cross-Coupling ReactionsCatalytic C–H Functionalization Methods