Development of high-voltage bipolar redox-active organic molecules through the electronic coupling of catholyte and anolyte structures
Jacob S. Tracy, Elena S. Horst, Vladislav A. Roytman, F. Dean Toste
Abstract
of 2.31 V and demonstrating 93.6% average coulombic efficiency, 86.8% energy efficiency, and 68.6% capacity retention over the course of 275 charge-discharge cycles and 5 cell polarity reversals. Finally, the superior performance of symmetric O-NRFBs is experimentally confirmed by comparing these results to an asymmetric flow battery constructed with a distinct phenothiazine catholyte and a distinct phthalimide anolyte on opposing sides of the cell.
Topics & Concepts
RedoxPhenothiazineChemistryMoleculePhthalimideCoupling (piping)Organic moleculesCoupling reactionCombinatorial chemistryInorganic chemistryMaterials scienceOrganic chemistryCatalysisMetallurgyPharmacologyMedicineAdvanced battery technologies researchElectrocatalysts for Energy ConversionElectrochemical Analysis and Applications