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Development of high-voltage bipolar redox-active organic molecules through the electronic coupling of catholyte and anolyte structures

Jacob S. Tracy, Elena S. Horst, Vladislav A. Roytman, F. Dean Toste

2022Chemical Science25 citationsDOIOpen Access PDF

Abstract

of 2.31 V and demonstrating 93.6% average coulombic efficiency, 86.8% energy efficiency, and 68.6% capacity retention over the course of 275 charge-discharge cycles and 5 cell polarity reversals. Finally, the superior performance of symmetric O-NRFBs is experimentally confirmed by comparing these results to an asymmetric flow battery constructed with a distinct phenothiazine catholyte and a distinct phthalimide anolyte on opposing sides of the cell.

Topics & Concepts

RedoxPhenothiazineChemistryMoleculePhthalimideCoupling (piping)Organic moleculesCoupling reactionCombinatorial chemistryInorganic chemistryMaterials scienceOrganic chemistryCatalysisMetallurgyPharmacologyMedicineAdvanced battery technologies researchElectrocatalysts for Energy ConversionElectrochemical Analysis and Applications
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