Completing the triad: synthesis and full characterization of homoleptic and heteroleptic carbonyl and nitrosyl complexes of the group VI metals
Jan Bohnenberger, Manuel Schmitt, Wolfram Feuerstein, Ivo Krummenacher, Burkhard Butschke, Jakub Czajka, Przemysław J. Malinowski, Frank Breher, Ingo Krossing
Abstract
The triad of group VI metalloradicals is now finally accessible <italic>via</italic> the oxidation of Cr/Mo/W(CO)<sub>6</sub> with the synergistic oxidative system Ag[F-{Al(OR<sup>F</sup>)<sub>3</sub>}<sub>2</sub>]/0.5 I<sub>2</sub>.
Topics & Concepts
HomolepticTriad (sociology)ChemistryGroup (periodic table)Characterization (materials science)Carbonyl groupPolymer chemistryPhotochemistryStereochemistryOrganic chemistryNanotechnologyMetalMaterials sciencePsychologyPsychoanalysisInorganic Fluorides and Related CompoundsMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexes