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Ultrafast carrier dynamics in a monolayer MoS<sub>2</sub> at carrier densities well above Mott density

Durga Prasad Khatua, Asha Singh, Sabina Gurung, Salahuddin Khan, Manushree Tanwar, Rajesh Kumar, J Jayabalan

2022Journal of Physics Condensed Matter19 citationsDOI

Abstract

Abstract Due to the growing interest in monolayer (ML) molybdenum disulfide (MoS 2 ) in several optoelectronic applications like lasers, detectors, sensors, it is important to understand the ultrafast behavior of the excited carriers in this material. In this article, a comprehensive study of the charge carrier dynamics of a monolayer MoS 2 flake has been studied using transient transmission technique near A-exciton under high excitation densities well above the Mott density. Fluence dependent studies has been carried out to understand the origin of the processes which modifies its optical response under excitation. The dissociation of excitons leads to an observed fast bandgap renormalization. At later times when large number of carriers relax the remaining carriers forms excitons leading to a bleaching effect.

Topics & Concepts

ExcitonMonolayerCharge carrierUltrashort pulseExcited stateChemical physicsBand gapMaterials scienceMolybdenum disulfideExcitationFluenceDissociation (chemistry)Condensed matter physicsCarrier lifetimeMolecular physicsChemistryCharge-carrier densityKerr effectMott insulatorUltrafast laser spectroscopyElectron mobilityTime-dependent density functional theoryCharge density waveOptoelectronicsPhotoluminescence2D Materials and ApplicationsStrong Light-Matter InteractionsChemical and Physical Properties of Materials
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