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Enantioselective synthesis of benzosilacyclohexanes with racemic benzosilacyclobutenes and diastereoselectivity reversal

Shaowei Chen, Zhiqiang Fang, Shanshan Liu, Xiaoqian He, Yu Lan, Xiao Shen

2025Science Bulletin18 citationsDOI

Topics & Concepts

StereocenterEnantioselective synthesisAlleneChemistryStereochemistryLigand (biochemistry)Substrate (aquarium)Carbon fibersStereoselectivitySubstrate specificityStereoisomerismChiral ligandCombinatorial chemistryReaction conditionsChemical synthesisChirality (physics)Asymmetric carbonAsymmetric Synthesis and CatalysisCyclopropane Reaction MechanismsSynthetic Organic Chemistry Methods
Enantioselective synthesis of benzosilacyclohexanes with racemic benzosilacyclobutenes and diastereoselectivity reversal | Litcius