UV-protection from chitosan derivatized lignin multilayer thin film
Thomas J. Kolibaba, Daniel L. Stevens, Stephen T. Pangburn, Olivia Condassamy, Martin Camus, Étienne Grau, Jaime C. Grunlan
Abstract
layer-by-layer (LbL) assembly with biologically sourced chitosan. The growth mechanism of this film is hypothesized to be a result of both hydrogen bonding and ionic interactions. The film demonstrates excellent UV-absorptive capability. A 100 nm thick chitosan/lignin coating was applied to a poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film and shown to reduce its degradation sixfold over the course of a 1 hour exposure to harsh UV light. This is the first demonstration of lignin being utilized in a fully biologically derived LbL film. Utilization of lignin in LbL assembly is an important step in the development of renewable nanotechnology.