Strong Electron Transfer in Covalently Integrating Cu(I)-Organic Frameworks Enabling Effective Radionuclide Capture
Liecheng Guo, Chang‐Zheng Tu, Yiwei Huang, Yuting Yang, Qing Yun Zhang, Zhiwu Yu, Feng Luo
Abstract
Rational construction of strong electron-transfer materials remains a challenging task. Herein, we show a design rule for the construction of strong electron-transfer materials through covalently integrating electron-donoring Cu(I) clusters and electron-withdrawing triazine monomers together. As expected, Cu-CTF-1 (Cu(I)-triazine framework) was found to enable strong electron transfer up to 0.46|e| from each Cu(I) metal center to each adjacent triazine fragment. This finally leads to good spatial separation in both photogenerated electron–hole pairs and function units for photocatalytic uranium reduction under ambience and no sacrificial agent and to good charge separation of [I + ][I 5 – ] for I 2 immobilization under extremely rigorous conditions. The results have not only opened up a structural design principle to access electron-transfer materials but also solved several challenging tasks in the field of radionuclide capture and CTFs.