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Modeling of Reversible Solid Oxide Cell Stacks with an Open-Source Library

Shidong Zhang, Roland Peters, Bob Varghese, Robert Deja, Nicolas Kruse, Steven Beale, L. Blum, Ralf Peters, Rüdiger‐A. Eichel

2022Journal of The Electrochemical Society12 citationsDOIOpen Access PDF

Abstract

This work describes a recently-developed numerical model for three-dimensional, steady-state simulations of reversible solid oxide cell (rSOC) stacks, taking into account a heterogeneous temperature field. The model employs a volume-averaged approach, also referred to as the distributed resistance analogy. It considers fluid flow, multi-component species diffusion, as well as heat and mass transfer, including thermal radiation and electrochemical reactions. The implementation of the computational model is based on an open-source library, OpenFOAM. An in-house designed rSOC stack, Mark-H is considered. Simulations are performed for repeating units with a 320 cm 2 active area, with both the present stack model and a one-dimensional Simulink model. Both models predict very similar voltages, with a maximum difference of 2% compared to experimental results. The present model shows a temperature distribution closer to the experimental data than the Simulink model, although a slightly longer simulation time is required.

Topics & Concepts

Stack (abstract data type)Work (physics)MechanicsDiffusionMass transferHeat transferSteady state (chemistry)OxideNuclear engineeringThermodynamicsMaterials scienceComputer scienceChemistryPhysicsEngineeringPhysical chemistryProgramming languageMetallurgyAdvancements in Solid Oxide Fuel CellsCatalysis and Oxidation ReactionsMagnetic and transport properties of perovskites and related materials
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