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Coupling Analysis of Chemiluminescence and Pressure Changes in CH<sub>4</sub>/Air Explosion Suppressed by NaHCO<sub>3</sub> Powder

Liwei Cui, Xiaobin Li, Guang Yang

2020ACS Omega10 citationsDOIOpen Access PDF

Abstract

powder added. Due to the test of different concentrations of suppression powder in 20 L spherical-explosion-test devices, the flame emission spectrum and explosion pressure data were collected. In this experiment, four kinds of excited radicals, including CN*, HCHO*, CO*, and OH*, have a higher probability of being detected, and the changes of their existence duration and spectral intensity show strong regularity. Results reveal that for suppressant concentration in the range of 0-50 mg/L, together with the improvement of a suppression effect, the existence duration and spectral intensity of CN*, CO*, and OH* decrease, which is opposite to that of HCHO*. Besides, the spectral intensity of OH* and CO* shows a good linear relationship with the change of the maximum explosion pressure. Controlling the content of CN*, CO*, OH*, and HCHO* is of great significance in suppressing the explosion.

Topics & Concepts

ChemiluminescenceCoupling (piping)High pressureMaterials scienceNuclear engineeringChemistryPhysicsThermodynamicsPhysical chemistryMetallurgyEngineeringCombustion and Detonation ProcessesEnergetic Materials and CombustionAdvanced Combustion Engine Technologies
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