Dual-Anion Strategy Induces Dual Enhancement Toward Ultrashort Phase-Matching Wavelength in Deep-UV Transparent d<sup>0</sup> Transition Metal Oxyfluorides
Dongdong Chu, Kewang Zhang, Congwei Xie, Keith T. Butler, Zhihua Yang, Shilie Pan
Abstract
The d 0 transition metal oxides are the most commonly used nonlinear optical (NLO) materials in the visible light region; however, their limited band gaps seriously hinder their application in ultraviolet (UV) and deep-ultraviolet (DUV) regions. Achieving the double enhancement of band gap and birefringence by regulating anionic units helps to push their phase-matching (PM) wavelength into UV/DUV regions. Herein, starting from the famous NLO material LiNbO 3, a “dual-anion strategy” is proposed to regulate the [NbO 6– x F x ] octahedra, and the predicted Li 2 Nb 2 O 6– x F 2 x ·(LiF) y ( x = 1, 2, 4; y = 0, 2) materials exhibit the dual-property magnification of wide band gaps (3.82–6.26 eV, 1–3 eV larger than LiNbO 3 ) and extraordinary birefringence (0.100–0.322, 1–4 times that of LiNbO 3 ), along with a strong second harmonic generation (SHG) response of 2.6–6.2 × KDP. Remarkably, Li 2 NbOF 5 -I and LiNbOF 4 -II have extremely short PM wavelength (λ PM = 209 nm) ever reported for d 0 transition metal oxyfluorides. Further analysis uncovers that the fluorinated modification of band edges and the increase of octahedral anisotropy in [NbO 6−x F x ] anionic groups are the main reasons for the enhanced PM ability.