Litcius/Paper detail

Influence of sputtering power on the switching and reliability of ferroelectric Al <sub>0.7</sub> Sc <sub>0.3</sub> N films

Ryota Shibukawa, Sung‐Lin Tsai, Takuya Hoshii, Hitoshi Wakabayashi, Kazuo Tsutsui, Kuniyuki Kakushima

2022Japanese Journal of Applied Physics21 citationsDOI

Abstract

Abstract The sputtering power dependence of 40 nm thick Al 0.7 Sc 0.3 N ferroelectric properties was characterized from 200 to 300 W. X-ray rocking curve revealed higher orientated growth into the c -axis with higher sputtering power. Films formed by high power showed reduced leakage current with a higher breakdown field, enabling one to apply the high field for ferroelectric switching. A high remnant polarization ( P r ) of 130 μ C cm −2 was obtained with a coercive field ( E c ) of 6 MV cm −1 . The switching cycle test revealed a wake-up effect for all the films; increasing the leakage current and modifying the E c . We anticipate the change is attributed to the existence and the generation of nitrogen vacancies ( V N ) in the films.

Topics & Concepts

FerroelectricitySputteringMaterials sciencePolarization (electrochemistry)CoercivityAnalytical Chemistry (journal)PolarNitrogenCondensed matter physicsOptoelectronicsThin filmChemistryNanotechnologyDielectricPhysicsAstronomyOrganic chemistryChromatographyPhysical chemistryFerroelectric and Piezoelectric MaterialsAcoustic Wave Resonator TechnologiesFerroelectric and Negative Capacitance Devices