Litcius/Paper detail

Removal of Methylene Blue Dye from Aqueous Solution Using Trichlorovinylsilane Chitosan–g–polyacrylamide Hydrogel

Anthony Udukhomo Awode, Sunday E. Elaigwu, Akeem Adeyemi Oladipo, Osman Salih Yılmaz, Mustafa Gazi

2023Journal of the Turkish Chemical Society Section A Chemistry13 citationsDOIOpen Access PDF

Abstract

A new hydrogel based on vinylsilane-chitosan and acrylamide was synthesized as VSi-CTS-g-PAAm and was used to remove methylene blue (MB) from aqueous solution using batch adsorption technique. The VSi-CTS-PAAm hydrogel interacted with methylene blue (MB) dye solution at different mass-liquid ratios, pH, and temperature. The amount of MB dye removal was estimated using a UV-Vis spectrophotometer at an optical density of λmax= 665 nm. The MB dye removal was most effective at pH 12, with about 98 % removal at 50 °C. The study's findings also indicated that the equilibrium data exhibited the highest degree of conformity with the Langmuir isotherm model. Additionally, the adsorption process adhered to the pseudo-second-order kinetics and was characterized as endothermic. Therefore, our study suggests that the utilization of prepared materials may have potential advantages in treating wastewater containing dyes.

Topics & Concepts

ChemistryMethylene blueAqueous solutionAdsorptionChitosanEndothermic processPolyacrylamideLangmuir adsorption modelAcrylamideNuclear chemistryChromatographySelf-healing hydrogelsChemical engineeringPolymer chemistryOrganic chemistryPolymerCopolymerCatalysisEngineeringPhotocatalysisAdsorption and biosorption for pollutant removalConducting polymers and applicationsElectrochemical sensors and biosensors