Poly(methylvinylsiloxane)-Based High Internal Phase Emulsion-Templated Materials (polyHIPEs)—Preparation, Incorporation of Palladium, and Catalytic Properties
Jan Mrówka, Mariusz Gackowski, Lidia Lityńska‐Dobrzyńska, Andrzej Bernasik, R. Kosydar, A. Drelinkiewicz, Magdalena Hasik
Abstract
∼8 nm, respectively). The Pd-containing polyHIPEs showed activity in catalytic hydrogenation of the triple carbon-carbon bond in phenylacetylene giving the unsaturated product, styrene with a selectivity of ca. 80%. To the best of our knowledge, this is the first work devoted to polysiloxane-based polyHIPEs with dispersed metallic particles.
Topics & Concepts
Materials sciencePolymerChemical engineeringPalladiumPhenylacetyleneCatalysisPolymer chemistryTetrahydrofuranPolymerizationPhase (matter)EmulsionMonomerCarbon fibersDivinylbenzenePorosityStyreneOrganic chemistryComposite numberChemistryCopolymerComposite materialSolventEngineeringPickering emulsions and particle stabilizationCovalent Organic Framework ApplicationsAdvanced Polymer Synthesis and Characterization