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Synthesis of homophthalimide spironaphthalenones through [5 + 1] spiroannulation of aryl/alkenyl enaminones with diazo homophthalimides

Chun Yang, Xinying Zhang, Xuesen Fan

2023Organic Chemistry Frontiers32 citationsDOI

Abstract

Presented herein is a novel synthesis of homophthalimide spironaphthalenones from the cascade reaction of enaminones with diazo homophthalimides.

Topics & Concepts

ChemistryDiazoArylMedicinal chemistryOrganic chemistryAlkylCyclopropane Reaction MechanismsCatalytic C–H Functionalization MethodsSynthesis and Catalytic Reactions
Synthesis of homophthalimide spironaphthalenones through [5 + 1] spiroannulation of aryl/alkenyl enaminones with diazo homophthalimides | Litcius