Acid–base resistant ligand-modified molybdenum–sulfur clusters with enhanced photocatalytic activity towards hydrogen evolution
Huili Zheng, Jianqiang Zhao, Jian Zhang, Qipu Lin
Abstract
The first trimeric [Mo IV 3 S 7 ] cluster of MoS-MBTZ containing both S and N coordination sites, obtained by ligand-modification engineering, displays high acid–base stability and excellent photocatalytic activity towards H 2 evolution.
Topics & Concepts
PhotocatalysisLigand (biochemistry)MolybdenumSulfurCluster (spacecraft)ChemistryBase (topology)PhotochemistryMaterials scienceInorganic chemistryCatalysisOrganic chemistryBiochemistryReceptorComputer scienceMathematicsMathematical analysisProgramming languageMetalloenzymes and iron-sulfur proteinsPolyoxometalates: Synthesis and ApplicationsNanocluster Synthesis and Applications