Reactions of an anionic chelate phosphane/borata-alkene ligand with [Rh(nbd)Cl]<sub>2</sub>, [Rh(CO)<sub>2</sub>Cl]<sub>2</sub> and [Ir(cod)Cl]<sub>2</sub>
Kohei Watanabe, Atsushi Ueno, Xin Tao, Karel Škoch, Xiaoming Jie, Sergei I. Vagin, Bernhard Rieger, Constantin G. Daniliuc, Matthias C. Letzel, Gerald Kehr, Gerhard Erker
Abstract
Borata-alkenes can serve as anionic olefin equivalent ligands in transition metal chemistry. A chelate ligand of this type is described and used for metal coordination.
Topics & Concepts
ChemistryChelationAlkeneLigand (biochemistry)Olefin fiberTransition metalMetalStereochemistryMedicinal chemistryRhodiumInorganic chemistryCatalysisOrganic chemistryReceptorBiochemistryOrganoboron and organosilicon chemistryOrganometallic Complex Synthesis and CatalysisAsymmetric Hydrogenation and Catalysis