Stabilization of polyiodide networks with Cu(<scp>ii</scp>) complexes of small methylated polyazacyclophanes: shifting directional control from H-bonds to I⋯I interactions
Álvaro Martínez‐Camarena, Matteo Savastano, José M. Llinares, Begoña Verdejo, Antonio Bianchi, Enrique García‐España, Carla Bazzicalupi
Abstract
Modulation of hydrogen bonds and iodine–iodine interactions, both covalent and supramolecular, unlocks novel possibilities for the construction of transition metal-polyiodide hybrid networks.
Topics & Concepts
Supramolecular chemistryHydrogen bondCovalent bondChemistryIodineTransition metalMetalPolymer chemistryCrystallographyOrganic chemistryMoleculeCrystal structureCatalysisMolecular Sensors and Ion DetectionSupramolecular Chemistry and ComplexesMetal-Organic Frameworks: Synthesis and Applications