Radical scavenging activity of carbon nanotubes: toward appropriate selection of a radical initiator
Taiyo Shimizu, Ryoichi Kishi, Takeo Yamada, Kenji Hata
Abstract
biomedicine, but for the materials industry. In this study, we report that carbon nanotubes (CNTs) can scavenge radicals from organic peroxides, while radicals from azo-type radical initiators exhibit only a few effects from the presence of CNTs. In addition, experimental results suggest the possibility that captured peroxide radicals generate active radical sites on the CNT surface, from which polymerization can take place. These results indicate the importance of selecting an appropriate radical initiator.
Topics & Concepts
RadicalCarbon nanotubeScavengingChemistryRadical polymerizationCobalt-mediated radical polymerizationPeroxidePhotochemistryRadical initiatorPolymerizationOrganic chemistryPolymerNanotechnologyMaterials scienceAntioxidantCarbon Nanotubes in CompositesFullerene Chemistry and ApplicationsTransition Metal Oxide Nanomaterials