Deprotonation-Induced and Ion-Pairing-Modulated Diradical Properties of Partially Conjugated Pyrrole–Quinone Conjunction
Shinya Sugiura, Takashi Kubo, Yohei Haketa, Yuta Hori, Yasuteru Shigeta, Hayato Sakai, Taku Hasobe, Hiromitsu Maeda
Abstract
Q uinoidal molecules based on di p yrrolyldiketone b oron complexes ( QPB s), in which pyrrole units were connected by a partially conjugated system as a singlet spin coupler, were synthesized. QPB, which was stabilized by the introduction of a benzo unit at the pyrrole β-positions, formed a closed-shell tautomer conformation that showed near-infrared absorption. The deprotonated species, monoanion QPB – and dianion QPB 2–, showing over 1000 nm absorption, were formed by the addition of bases, providing ion pairs in combination with countercations. Diradical properties were observed in QPB 2–, whose hyperfine coupling constants were modulated by ion-pairing with π-electronic and aliphatic cations, demonstrating cation-dependent diradical properties. VT NMR and ESR along with a theoretical study revealed that the singlet diradical was more stable than the triplet diradical.