Litcius/Paper detail

The Effect of UV Aging on the Structure of PVC in the Presence of Organotin(IV) Compounds

Muna Bufaroosha, Nadia Salih, Angham G. Hadi, Dina S. Ahmed, Mohammed H. Al‐Mashhadani, Emad͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏͏ Yousif

2020Al-Nahrain Journal of Science25 citationsDOIOpen Access PDF

Abstract

New photostabilizers of poly(vinyl chloride) (PVC) were synthesized and investigated the photostabilizing efficiency of the polymer films by ultraviolet (UV) experiment. The rate of photodecomposition constant have been calculated for PVC films as a method for evaluating the efficiency of the organotin(IV) complexes that used as a photostabilizers after 300 hour of irradiation. The results have showed that the additives had reduced the rate of photodecomposition constant of PVC films significantly with comparison to PVC (blank). The (kd) value for PVC films was the highest in the absence of any additives, and the lowest value in the presence of triphenyltin (IV) complex.

Topics & Concepts

Vinyl chloridePolyvinyl chlorideUltravioletPolymerReaction rate constantIrradiationPolymer chemistryChemistryChlorideUltraviolet irradiationUltraviolet radiationMaterials scienceNuclear chemistryKineticsOrganic chemistryRadiochemistryCopolymerPhysicsNuclear physicsOptoelectronicsQuantum mechanicsPolymer Science and PVCPolymer Nanocomposites and PropertiesPolymer crystallization and properties