Thin-film composite (TFC) membranes incorporated with hydrophilic additives and layered double hydroxides (LDHs) for effective brackish water (BW) desalination
Jie Gao, Ji Wu, Shing Bor Chen, Tai-Shung Chung
Abstract
To overcome the limited water permeability of thin-film nanocomposite (TFN) membranes for brackish water reverse osmosis (BWRO) processes, we have incorporated a few amine or hydroxyl group terminated hydrophilic additives during interfacial polymerization when fabricating RO membranes and found that the membrane comprising 1 wt% 2-(2-hydroxyethyl)pyridine (2-(2-pyridyl)ethylahydroxide, PEH) has the best BWRO performance. The membrane was subsequently infiltrated with layered double hydroxide (LDH) nanoparticles by a post ethanol activation and could deliver a water permeability of 4.18 LMH bar −1 which is 100 % more than the control membrane without much compromising the salt rejection. The newly developed process not only incorporates nanofillers with the advantages of simplicity and decoupling from the interfacial polymerization process, but also endows the TFN membranes with enhanced separation performance. The study may provide useful insights to incorporate nanofillers by the solvent activation approach for the fabrication of TFN membranes. • TFC BWRO membranes comprising LDHs were developed by solvent activation. • Membranes made from additive PEH has a 75 % increase in pure water permeability (P w ). • Ethanol post-treatment can enhance P w of TFC RO membranes significantly. • MgAl LDH functionalization is very effective to enhance membrane performance. • The best membrane has a P w of 4.18 LMH bar −1 and a NaCl rejection of 97.1 %.