Litcius/Paper detail

Effect of the Oxygen Concentration and Temperature on Thermal Decomposition of N<sub>2</sub>O in an Inert Gas

Jae Geun Yun, Han Min Lee, Gwang Yeol Baik, Ji Yeop Kim, Sang Ji Lee, Min Kyu Jeon, Sang In Keel, Jung Goo Hong

2021ACS Omega15 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide Nitrous oxide (N 2 O) is one of the greenhouse gases that contribute to global warming. But, there are few methods for controlling N 2 O directly. It is essential to reduce N 2 O to solve environmental problems. In this study, we investigate the O 2 concentration dependence of N 2 O decomposition under an argon-based gas mixture in a high-temperature thermal reactor. The gas concentrations are calculated using CHEMKIN. The results confirm that more N 2 O is converted to N 2 or NO at lower O 2 concentrations. Therefore, the conversion process is hindered by increasing the O 2 concentration. We propose a modified parameter of N 2 O decomposition, and it is employed in the CHEMKIN calculations. With the modified parameter, the experimental results are in a similar tendency to the calculated results.

Topics & Concepts

CHEMKINNitrous oxideThermal decompositionDecompositionInert gasOxygenArgonThermalChemistryGreenhouse gasMaterials scienceOutgassingThermodynamicsAnalytical Chemistry (journal)Environmental chemistryPhysical chemistryCombustionOrganic chemistryEcologyBiologyPhysicsCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsAdvanced Combustion Engine Technologies