Facet-Dependent Photocatalytic Behavior of Rutile TiO<sub>2</sub> for the Degradation of Volatile Organic Compounds: In Situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy and Density Functional Theory Investigations
Wenjie Zhou, Fang Chen, Mengmeng Li, Qin Cheng, Juan Deng, Pengcheng Wang, Mengdie Cai, Song Sun
Abstract
In this study, a custom rutile titanium dioxide (TiO 2 ) photocatalyst with a single exposed surface was utilized to investigate the facet-dependent photocatalytic mechanism of toluene. The degradation of toluene was dynamically monitored using diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) technology coupled with theoretical calculations. The findings demonstrated that the photocatalytic degradation rate on the TiO 2 (001) surface was nearly double that observed on the TiO 2 (110) surface. This remarkable enhancement can be attributed to the heightened stability in the adsorption of toluene molecules and the concurrent reduction in the energy requirement for the ring-opening process of benzoic acid on the TiO 2 (001) surface. Moreover, the TiO 2 (001) surface generated a greater number of reactive oxygen species (ROS), thereby promoting the separation of photogenerated charge carriers and concurrently diminishing their recombination rates, amplifying the efficiency of photocatalysis. This research provides an innovative perspective for a more comprehensive understanding of the photocatalytic degradation mechanism of TiO 2 and presents promising prospects for significant applications in environmental purification and energy fields.