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Equilibrium, Kinetic Data, and Adsorptıon Mechanism for Lead Adsorptıon onto Polyacrylamıde Hydrogel

Imane Lebkiri, Brahim Abbou, Lamya Kadiri, Abdelkarim Ouass, Abdelhay El Amri, Hanae Ouaddari, Omar Elkhattabi, Ahmed Lebkiri, El Houssine RİFİ

2021Journal of the Turkish Chemical Society Section A Chemistry14 citationsDOIOpen Access PDF

Abstract

The present study focuses on the effect of experimental parameters (pH, temperature, gel mass, metal concentration, contact time) on the performance of lead adsorption by polyacrylamide hydrogels. The results obtained showed that the retention of Pb2+ ions is closely linked to these parameters. The adsorbent gels equilibrate with the metal solution after 180 minutes, and the maximum adsorption capacity is 442.31 mg/g. In addition, the adsorption obeys the pseudo-second-order kinetics and Langmuir isotherm. Desorption of the micropollutant retained by the hydrogel was also studied using 0.1 M of HCl solution. The desorption was rapid, and the efficiency exceeded 90% after a contact time of 90 minutes.

Topics & Concepts

ChemistryAdsorptionDesorptionPolyacrylamideKineticsLangmuir adsorption modelSelf-healing hydrogelsChromatographyKinetic energyMetal ions in aqueous solutionLangmuirChemical engineeringMetalAqueous solutionAnalytical Chemistry (journal)Polymer chemistryOrganic chemistryPhysicsEngineeringQuantum mechanicsAdsorption and biosorption for pollutant removalNanomaterials for catalytic reactions
Equilibrium, Kinetic Data, and Adsorptıon Mechanism for Lead Adsorptıon onto Polyacrylamıde Hydrogel | Litcius