FeCoNi Ternary Nano-Alloys Embedded in a Nitrogen-Doped Porous Carbon Matrix with Enhanced Electrocatalysis for Stable Lithium–Sulfur Batteries
Yang Lin, Jianchao Li, Wenju Xie, Zhiyong Ouyang, Jie Zhao, Yanhe Xiao, Shuijin Lei, Baochang Cheng
Abstract
The application of composite materials that combine the advantages of carbonaceous material and metal alloy proves to be a valid method for improving the performance of lithium–sulfur batteries (LSBs). Herein iron–cobalt–nickel (FeCoNi) ternary alloy nanoparticles (FNC) that spread on nitrogen-doped carbon (NC) are obtained by a strategy of low-temperature sol–gel followed by annealing at 800 °C under an argon/hydrogen atmosphere. Benefiting from the synergistic effect of different components of FNC and the conductive network provided by the NC, not only can the “shuttle effect” of lithium polysulfides (LiPS) be suppressed, but also the conversion of LiPS, the diffusion of Li +, and the deposition of Li 2 S can be accelerated. Taking advantage of those merits, the batteries assembled with an FNC@NC-modified polypropylene (PP) separator (FNC@NC//PP) can deliver a high reversible specific capacity of 1325 mAh g –1 at 0.2 C and maintain 950 mAh g –1 after 200 cycles, and they can also achieve a low capacity fading rate of 0.06% per cycle over 500 cycles at 1 C. More impressively, even under harsh test conditions (the ratio of electrolyte to sulfur (E/S) = 6 μL mg –1 and sulfur loading = 4.7 mg cm –2 and E/S = 10 μL mg –1 and sulfur loading = 5.9 mg cm –2 ), the area capacity of batteries is still much higher than 4 mAh cm –2 .