Recent progress in rare-earth metal-catalyzed sp<sup>2</sup> and sp<sup>3</sup> C–H functionalization to construct C–C and C–heteroelement bonds
Kapileswar Seth
Abstract
The review presents rare-earth metal-catalyzed C(sp 2 /sp 3 )–H functionalization accessing C–C/C–heteroatom bonds and olefin (co)polymerization, highlighting substrate scope, mechanistic realization, and origin of site-, enantio-/diastereo-selectivity.
Topics & Concepts
ChemistryRare earthSurface modificationCatalysisMetalOrganic chemistryPhysical chemistryMineralogyCatalytic C–H Functionalization MethodsAsymmetric Hydrogenation and CatalysisCarbon dioxide utilization in catalysis