Copper-catalyzed silylation of aryl and alkenyl triflates with silylboronic esters avoiding base-mediated borylation
Shintaro Kamio, Masaaki Nakamoto, Takehiro Yamagishi, Martin Oestreich, Hiroto Yoshida
Abstract
-butylphosphine and 4,4'-diphenyl-2,2'-bipyridine as a ligand combination turned out to be indispensable for achieving the high catalytic activity.
Topics & Concepts
BorylationSilylationArylChemistryCatalysisBase (topology)CopperCombinatorial chemistryOrganic chemistryMedicinal chemistryMathematicsMathematical analysisAlkylCatalytic Cross-Coupling ReactionsOrganoboron and organosilicon chemistryCatalytic C–H Functionalization Methods