Quantitative reaction monitoring using <i>para</i>hydrogen-enhanced benchtop NMR spectroscopy
Alastair D. Robinson, Fraser Hill-Casey, Simon B. Duckett, Meghan E. Halse
Abstract
The para hydrogen-induced polarisation (PHIP) NMR signal enhancement technique is used to study H 2 addition to Vaska’s complex ( trans -[IrCl(CO)(PPh 3 ) 2 ]) and a mixture of Vaska’s complex derivatives with benchtop (1 T) NMR detection.
Topics & Concepts
ChemistryNuclear magnetic resonance spectroscopyHydrogenSpectroscopyProton NMRAnalytical Chemistry (journal)Physical chemistryStereochemistryOrganic chemistryPhysicsQuantum mechanicsAdvanced NMR Techniques and ApplicationsAtomic and Subatomic Physics ResearchNMR spectroscopy and applications