On/off porosity switching and post-assembly modifications of Cu<sub>4</sub>L<sub>4</sub> metal–organic polyhedra
Witold M. Bloch, Ravichandar Babarao, Matthew L. Schneider
Abstract
). Further control over the crystal packing of MOPs is achieved through covalent post-assembly modifications, which promote the crystallisation of isoreticular 2-D sheet-like structures.
Topics & Concepts
PolyhedronPorosityCovalent bondMaterials scienceMetalRigidity (electromagnetism)CrystallographyMetal-organic frameworkNanotechnologyChemistryMetallurgyComposite materialOrganic chemistryGeometryMathematicsAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsNanocluster Synthesis and ApplicationsPolyoxometalates: Synthesis and Applications