Hydrogen Storage in Mg–Ni-Type Alloys with La and Sm Incorporation
Yiwan Chen, Hui Yong, Shuai Wang, Xiuzhi Zhang, Wei Zhang, Kai Feng, Jifan Hu, Yanghuan Zhang
Abstract
The addition of rare earth elements lanthanum and samarium to Mg–Ni-type alloys enhanced the hydrogen absorption and desorption kinetics. The microstructures of these alloys were characterized by using XRD, SEM, TEM, HTREM, and SAED methods. PCT equipment was employed to test the hydrogen storage performance. It was observed that Mg 96 NiLa 3 alloys exhibited a more uniform and refined phase distribution, credited to the grain refinement effect triggered by Mg 17 La 2 . Additionally, the Mg 96 NiLa 3 alloy demonstrated a significant hydrogen storage capacity, with hydrogen release reaching 6.2 wt % at 593 K, compared to 5.4 wt % for the Mg 96 NiSm 3 alloy at the same temperature. The activation energies of dehydrogenation for Mg 96 NiLa 3 and Mg 96 NiSm 3 were 99.69 and 97.53 kJ/mol, respectively, with no significant difference considering errors. Similarly, the enthalpies of dehydrogenation were 72.9 kJ/mol of H 2 for Mg 96 NiLa 3 and 78 kJ/mol of H 2 for Mg 96 NiSm 3, indicating no notable distinction in the thermodynamic properties of the two alloys. Thus, the enhancement of the thermodynamic properties of Mg–Ni-type alloys by rare earth elements La and Sm appears to be insignificant.