Zn(<scp>ii</scp>) and Cd(<scp>ii</scp>) coordination polymers with a new angular bis-pyridyl-bis-amide: synthesis, structures and sensing properties
Xiang‐Kai Yang, Wei‐Te Lee, Ji‐Hong Hu, Jhy‐Der Chen
Abstract
Zn(<sc>ii</sc>) and Cd(<sc>ii</sc>) coordination polymers that show a 2D double layer with the rare (4<sup>6</sup>·6<sup>4</sup>)-5 L4 topology and a 3D framework with a new (4·5·6)(4<sup>5</sup>·5<sup>5</sup>·6<sup>9</sup>·7·8) topology, respectively, show good selectivity toward the detection of Fe<sup>3+</sup> ions.
Topics & Concepts
SelectivityAmidePolymerIonCrystallographyTopology (electrical circuits)ChemistryStereochemistryOrganic chemistryCombinatoricsCatalysisMathematicsMetal-Organic Frameworks: Synthesis and ApplicationsMolecular Sensors and Ion DetectionCrystallography and molecular interactions