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Manipulation of Rashba splitting and thermoelectric performance of MTe (M = Ge, Sn, Pb) <i>via</i> Te off-centering distortion

Tianyu Wang, Kaixiang Hu, Xinlei Duan, Jingyi Zhang, Jia‐Yue Yang, Linhua Liu

2022RSC Advances10 citationsDOIOpen Access PDF

Abstract

lone electron pair of the cation, leading to the formation of strong anharmonic bonds in the original high-symmetry crystalline solids. The changes of the phonon dispersion and electronic structure also affect the electron-phonon scattering and scattering mechanism of MTe, which then manipulates the electrical transport properties. This work unravels the underlying physics on how the local Te off-centering distortion manipulates Rashba spin splitting and improves the thermoelectric performance of MTe.

Topics & Concepts

Distortion (music)Thermoelectric effectMaterials scienceCrystallographyChemistryCondensed matter physicsPhysicsOptoelectronicsQuantum mechanicsAmplifierCMOSAdvanced Thermoelectric Materials and DevicesHeusler alloys: electronic and magnetic propertiesChalcogenide Semiconductor Thin Films
Manipulation of Rashba splitting and thermoelectric performance of MTe (M = Ge, Sn, Pb) <i>via</i> Te off-centering distortion | Litcius