The simplest Diels–Alder reactions are not <i>endo</i>-selective
William J. Lording, Thomas Fallon, Michael S. Sherburn, Michael N. Paddon‐Row
Abstract
-selective. Trends in behaviour are traced to steric and electronic effects in Diels-Alder transition structures, giving new insights into these fundamental processes.
Topics & Concepts
Diels–Alder reactionSelectivityDeuteriumChemistryComputational chemistryOrganic chemistryCatalysisPhysicsNuclear physicsOrganic Chemistry Cycloaddition ReactionsAdvanced Chemical Physics StudiesAsymmetric Synthesis and Catalysis