Investigation of the optimum vibration energy harvesting performance of electrospun PVDF/BaTiO <sub>3</sub> nanogenerator
Harun Güçlü, Hasan Kasım, Murat Yazıcı
Abstract
The piezoelectric vibration energy harvesting performance of an electrospun poly(vinylidene fluoride) (PVDF)/Barium Titanate (BaTiO 3 ) nanocomposite piezo polymer nanogenerator was investigated in this study. To obtain the highest piezoelectric output value, electrospinning was performed using four distinct solvent volume ratios of Acetone/Dimethylformamide (DMF) of 0:10, 2:8, 4:6, and 6:4 and three different PVDF weight percent polymer concentrations of 10, 15, and 20. Additionally, three distinct BaTiO 3 addition weight percents of 5, 10, and 15 were investigated. The optimal concentration of PVDF (15 wt.%) was combined with a 6:4 volume ratio of Acetone/DMF to form a nanocomposite piezo polymer nanogenerator. The morphology and crystalline structure of PVDF and PVDF/BaTiO 3 were analyzed using Fourier-transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) techniques. Nanocomposite piezo polymer nanogenerator was manufactured to harvest energy from vibration. A cantilever beam was developed without a tip mass type system for piezoelectric energy harvesting tests. The highest piezoelectric power output was obtained as 0.243 μW (15 wt.% PVDF and 5 wt.% BaTiO₃), Acetone/DMF (6:4 vol./vol.)) under 10 MΩ at the 15.7 Hz resonance frequency. The morphology of electrospun nanofibers has a significant impact on the piezoelectric performance of a nanocomposite piezo polymer nanogenerator at high-amplitude vibration.