Electrophilicity of neutral square-planar organosilver(<scp>iii</scp>) compounds
Daniel Joven‐Sancho, Luca Demonti, Antonio Martı́n, Nathalie Saffon‐Merceron, Noel Nebra, Miguel Baya, Babil Menjón
Abstract
Ag(L) compounds with hard and soft Group 15 donor ligands, L, the metal center has been found to exhibit substantial acidity favouring apical coordination of an additional ligand under no coordination constraints.
Topics & Concepts
DenticityElectrophileChemistryLigand (biochemistry)CrystallographyPlanarSquare (algebra)StereochemistryOrganic chemistryComputer scienceCrystal structureBiochemistryReceptorComputer graphics (images)CatalysisMathematicsGeometryMagnetism in coordination complexesNanocluster Synthesis and ApplicationsMolecular Junctions and Nanostructures