Syntheses, crystal structures and supramolecular assemblies of two Cu(<scp>ii</scp>) complexes based on a new heterocyclic ligand: insights into C–H⋯Cl and π⋯π interactions
Samit Pramanik, Sudipta Pathak, Antonio Frontera, Subrata Mukhopadhyay
Abstract
A new heterocyclic ligand, N 3 L [4-(1-methylimidazole)-2,6-di(pyrazinyl)pyridine] and two Cu( ii ) complexes have been synthesized and characterized by several spectroscopic and DFT methods.
Topics & Concepts
Supramolecular chemistryLigand (biochemistry)PyridineChemistryCrystal structureStereochemistryCrystallographyCombinatorial chemistryMedicinal chemistryReceptorBiochemistryMetal complexes synthesis and propertiesMagnetism in coordination complexesSynthesis and Reactivity of Heterocycles